By J. F. Coetzee, D. Frollini (auth.), Gleb Mamantov (eds.)

This publication contains contributions through contributors within the Symposium "Spectroscopic and Electrochemical Characterizat.ion of Solute Species in Non~Aqueous Solvents" which happened on the American Chemical Society assembly, department of Analytical Chemistry, August 31 and September I, 1976, San Francisco, California. The manuscripts have been submitted to the editor throughout the first 1/2 1977 and, in general, characterize stories of chosen examine themes within the vast sector of characterization of solute species in non~aqueous solvents. In organizing this Symposium, i tried to assemble a considerably huge crew of study employees serious about spectro­ scopic and electrochemical reports within the 3 huge periods of non-aqueous solvents ~ natural solvents, covalent inorganic sol­ vents and molten salts. The experimental apprcaches and difficulties, akin to avoidance of lines of moisture and oxygen, are often related for all sorts of non-aqueous solvents. it's was hoping that this quantity might be invaluable to all inquisitive about chemistry in non-aqueous solvents. Gleb l>lamantov , Contents 1. identity AND SYSTEMIZATION OF SOLVENT houses considering THE LIGAND SUBSTITUTION KINETICS OF LABILE COMPLEXES OF NICKEL(II) J. F. Coetzee, D. Frollini, C. G. Karakatsanis, E. J.

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39 (1970). 748 (1976). Karakat~anis, ::!.. 3104 ::!.. ::!.. Amer. Chern. , Amer. Chern. , 87, unpublished, preliminary Chern. , Dalton, 1602 (1973). F. COETZEE ET AL. (56) H. P. Bennetto and E. F. Caldin, J. Chern. Soc. A, 2191, 2198, 2207 (1971); H. P. Bennetto, ibid~, 2211 (1971)~ (57) J. A. Riddick and W. B. Bunger, "Organic Solvents," WileyInterscience, New York (1970). (58) T. B. Reddy, Pure ~. , (59) J. Juillard, Pure ~. , in press. (60) J. F. Coetzee, Pure Appl. Chern. , ~, 427 (1966) .

G. Pearson and O. P. Anderson, Inorg. , (47) R. B. Jordan, Inorg. (48) W. J. MacKellar ancl D. B. Rorabacher, 93, 4379 (1971). (49) J. F. Coetzee and G. R. Padman abh an , 5005 (1965). (50) J. F. Coetzee and C. G. results. (51) P. W. Buck, (52) F. Dickert and H. Hoffmann, Ber. Bunsenges. Phys. , 75, -- -- 1320 (1971). (53) F. Dickert, H. Hoffmann, and W. Jaenicke, Ber. Bunsenges. Phys. , 74,500 (1970). (54) H. Hoffmann, T. Janjic, and R. Sperati, Ber. Bunsenges, Phys. , ~, 223 (1974). (55) A. Diamond, A.

72) J. F. Coetzee and D. M. Gilles, Inorg. , (73) M. L. Sanduja and W. M. Smith, Canad. (1973) . (74) W. M. Smith, private communication, 1975; preliminary value for pyridine. (75) J. F. Coetzee and C. G. Karakatsanis, Inorg. , (1976) . ~. ~, 459 (1971). ~. ~, Chern. , ~, 3109 (1976) . :2, 275 (1971) . 400 1379 (1967). 217 ~, Chern. Soc. Dalton, 2082 (1974). ~. , 405 (1976). ~, 3975 ~, 3112 LIGAND AND SUBSTITUTION KINETICS 31 (76) J. F. Coetzee and D. , to be published. (77) J. F. Coetzee and K.

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