By E. Wolfram
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Extra so than any of the opposite significant teams of parts within the periodic desk, the transition metals have formed human heritage and feature been the workhorses of undefined. the invention of steel copper ended the Stone Age and ushered within the Bronze Age. Alloys of iron (especially metal) later took over, and the Iron Age changed the Bronze Age.
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Extra info for Colloid and Surface Science. Plenary and Main Lectures Presented at the International Conference on Colloid and Surface Science, Budapest, Hungary, 15–20 September 1975
D. Parfitt, Progress in Surface and Membrane Science. Academic Press, New York (1976). 19 A. C. Zettlemoyer, R. D. Iyengar and P. Scheidt, /. Colloid Interface Sci. 22, 172 (1966). 20 F. J. Micale, Y. K. Lui and A. C. Zettlemoyer, Disc. Faraday Soc. 42, 238 (1966). 418 2I G. D. PARFITT 0. Griot, Trans. Faraday Soc. 62, 2904 (1966). J. B. Peri, /. Phys. Chem. 69, 211 (1965). 23 E. P. Parry, /. Catalysis 2, 371 (1963). 24 N. W. Cant and L. H. Little, Can. J. Chem. 43, 1252 (1965). 25 K. H. Bourne, F.
1, p. 207. Chemical Society, London (1973). 3a H. Freundlich, Kapillarchemie II, pp. 378, 447; Akad. Verlag, Leipzig (1932); E. J. W. Verwey and J. Th. Overbeek, Theory of the Stability of Lyophobic Colloids, pp. 8, 9. Elsevier Amsterdam (1948). 3b E. J. W. Verwey, Discuss. Faraday Soc. 42, 314 (1966). 4 R. H. Ottewill, Non-ionic Surfactants (edited by M. J. Schick, Chap. 19, Dekker, New York (1967). L. Barclay and R. H. Ottewill, Special Discuss. Faraday Soc. 1, 169 (1970); see also Ref. 2. 5 D.
For titanium dioxide the situation is becoming clearer. r. investigations on the titania surface. Although there are some differences in detail in the assignments between the authors there would now seem reasonable justification for assuming that on the surface of rutile two distinct types of isolated hydroxyl group exist in different stereochemical environments. Parfitt et ai conclude that one of these is associated with a metal site having monodentate attachment (terminal OH) and the other on an oxide site with bidentate attachment (bridged OH).
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