By Frederick G. Mann, Arnold Weissberger
The Chemistry of Heterocyclic Compounds, considering its inception, has been famous as a cornerstone of heterocyclic chemistry. each one quantity makes an attempt to debate all facets – houses, synthesis, reactions, physiological and business value – of a particular ring method. to maintain the sequence up to date, supplementary volumes protecting the new literature on every one person ring process were released. Many ring platforms (such as pyridines and oxazoles) are taken care of in specified books, every one along with separate volumes or components facing various person themes. With all authors are well-known professionals, the Chemistry of Heterocyclic Chemistry is taken into account around the world because the critical source for natural, bioorganic, and medicinal chemists.
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Extra resources for Heterocyclic Derivatives of Phosphorous, Arsenic, Antimony and Bismuth (The Chemistry of Heterocyclic Compounds, Volume 1, 2nd Edition)
Yield (yo) 2 3 4 5 6 219' 205-206O 56 147- 150' 19 132-138' 160-1 63" 73 44 61 All these compounds should be capable of self-quaternization. The actual results are of considerable interest. The compound (21 ; n = 2) in I CHZCH2Br (21: >1 = 2) \ I CH-CHI (24) Ph Ph Ph Ph 2Br Ph Ph Ph Ph (23) boiling benzonitrile gives the tricyclic dibromide (22), i . e . Jtetradeca- 1,3,9,10tetraene dibromidc, [RlS -1, m p . p. 325-330", which when heated with an equivalent of 1,2dibromoethane also gave the dibromide (22).
P. p. 228-230", is formed as a 'by-product' in this reaction, and also (in 10% yield) when certain iron carbonyls (p. 14) are heated with benzylphosphonous dibromide in benzene at 170' for 16 hours. p. 240-241", has been isolated. Pentaphenylphosphole has a strong green fluorescence, its oxide has a bright yellow fluorescence, and its sulfide and selenide have none : the fluorescence of this phosphole (4 ; R = C,H,) is stronger than that of analogous phospholes in which the 1-phenyl group is replaced by an nlkyl group.
These results are consistent only with the 3-phospholene nucleus throughout this series. The large ~ i n y l - ~ lcoupling P which is common t o all the above compounds except the phosphine (31)is associated with the positive charge on the phosphorus atom in compounds such as phosphine oxides, phosphonium salts, and halogenophosphoranes (cf. Wiley and Stine "), and it indicates that the dichloro compound (28)in deuteriochloroform solution is ionic (as shown) and not quinquecovalent. 39 Another investigation (Quin and Barket 43) provided confirmation that the isoprene-phenylphosphonous dichloride adduct and its hydrolysis product, originally thought to have the 3-phospholene structures (33)and (34),respectively, have in fact the 2-phospholene structures (35, covalent or ionic) and (36), respectively.
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