By Christian M. Rojas

Designed for practitioners of natural synthesis, this e-book is helping chemists comprehend and make the most of rearrangement reactions to reinforce the synthesis of invaluable chemical compounds.

  • Provides prepared entry to the genesis, mechanisms, and artificial application of rearrangement reactions
  • Emphasizes strategic artificial making plans and implementation
  • Covers 20 diverse rearrangement reactions
  • Includes functions for synthesizing compounds beneficial as ordinary items, medicinal compounds, sensible fabrics, and actual natural chemistry

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Extra info for Molecular Rearrangements in Organic Synthesis

Sample text

33 Total synthesis of cladiellins by the Clark group utilizing an (E)selective [2,3]-shift. 34 Effective [1,2]-shift of oxonium ylides bearing benzylic migrating groups. 35 Oxonium ylide [1,2]-shifts and possible alternative reactivities. 36 [1,2]-Shifts of acetal-derived oxonium ylides. 37 Dactylol approach using oxonium ylide [1,2]-shift. 38 Approach to the tricyclic daphnane/tigliane skeleton via [1,2]-shift. 39 Construction of zaragozic acid core by Brogan and Zercher via [1,2]shift of ketal-derived oxonium ylide.

7 Four different varieties of Pummerer products. 8 Application of Pummerer rearrangement to the synthesis of modified furanosides. 9 Hydroxy aldehydes as intermediates in the synthesis of nelfinavir and analogues of mannostatin A. 10 Thionium ion generated by Pummerer chemistry as substrate in ene reaction. 11 Pummerer reaction in the synthesis of indolizine alkaloids. 12 Synthesis of CDE core of erinacine E. 13 Application of Pummerer rearrangement to the synthesis of complex thiols. 1 Cyclotriguaiacylene.

37 Dactylol approach using oxonium ylide [1,2]-shift. 38 Approach to the tricyclic daphnane/tigliane skeleton via [1,2]-shift. 39 Construction of zaragozic acid core by Brogan and Zercher via [1,2]shift of ketal-derived oxonium ylide. 1 Solanoeclepin A right segment synthesis and [2,3]-Wittig rearrangement. The Newman-like projections in the dashed circles indicate transition state bond formation. 3 [2,3]-Wittig rearrangement on Hajos–Parrish ketone derivative. 4 [2,3]-Wittig rearrangement on a 3-alkynyl dihydropyran ring.

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